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Acetamiprid Cartap
Etofenprox Imazethapyr
Metalaxyl-M Nicosulfuron
Thiamethoxam Clopyralid
Emamectin Benzoate Fenoxaprop-p-ethyl
Bacillus Thuringiensis Metsulfuron
Penconazole Abamectin
Tebuconazole Tribenuron
Kresoxim-methyl Bispyribac-Sodium

Products >> Fungicides >> Trifloxystrobin

Trifloxystrobin 95%TC
Trifloxystrobin 50%SC
Trifloxystrobin 50%WG
Trifloxystrobin 40%+pyrimethanil 12%SC

Trifloxystrobin NOMENCLATURE
Common name trifloxystrobin (BSI, pa ISO)
IUPAC name methyl (E)-methoxyimino-{(E)--[1-(,,-trifluoro-m-tolyl)ethylideneaminooxy]-o-tolyl}acetate
Chemical Abstracts name methyl (E)--(methoxyimino)-2-[[[(E)-[1-[3-(trifluoromethyl)phenyl]ethylidene]amino]oxy]methyl]benzeneacetate
CAS RN [141517-21-7]; [221007-60-9] former number Development codes CGA 279202

Mol. wt. 408.4 M.f. C20H19F3N2O4 Form Odourless, white solid. M.p. 72.9 °C B.p. c. 312 °C (decomp. starts at 285 °C) V.p. 3.4  10-3 mPa (25 °C) KOW logP = 4.5 (25 °C) Henry 2.3  10-3 Pa m3 mol-1 (25 °C) S.g./density 1.36 (21 °C) Solubility In water 610 g/l (25 °C). Stability Hydrolysis DT50 11.4 w (pH 7); stable at pH 5. Aqueous photolysis DT50 31.5 h (pH 7, 25 °C).

History Reported by P. Margot et al. (Proc. Br. Crop Prot. Conf. - Pests Dis., 1998, 2, 375). Introduced by Novartis Crop Protection AG (became Syngenta AG) in Switzerland, South Africa and USA in 1999. All rights sold to Bayer AG in 2000. Patents EP 00460575 Manufacturers Bayer CropScience

Trifloxystrobin APPLICATIONS
Biochemistry Inhibits mitochondrial respiration by blocking electron transfer at the Qo centre of cytochrome bc1. Mode of action Mesostemic, broad-spectrum fungicide with preventative and specific curative activity and displaying rain-fastness. Redistributed by superficial vapour movement and also has translaminar activity. Uses Broad spectrum fungicide for foliar use on a wide range of agricultural and horticultural crops in temperate, sub-tropical and tropical climates in open fields or protected under glass and plastic. In Europe its uses will be focussed on cereals (at 50 g/ha), grapes (at 187.5 g/ha), pome fruit (at 75 g/ha), and cucurbit crops (at 187.5 g/ha).Trifloxystrobin is active against fungi in all four classes - Ascomycetes, Deuteromycetes, Basidiomycetes and Oomycetes. Formulation types EC; SC; WG. Selected products: 'Flint' (Bayer CropScience); 'Tega' (Bayer CropScience); mixtures: 'Stratego' (+ propiconazole) (Bayer CropScience)

'Buy' (Me2); 'Compass' (Bayer CropScience); 'Gem' (Bayer CropScience); 'Twist' (Bayer CropScience); 'Zatao' (Bayer CropScience) mixtures: 'Eclair' (+ cymoxanil) (Bayer CropScience); 'Rombus' (+ propiconazole) (Bayer CropScience); 'Sphere' (+ cyproconazole) (Bayer CropScience) Discontinued products mixtures: 'Agora' * (+ cyproconazole) (Bayer)

Oral Acute oral LD50 for rats >5000 mg/kg. Skin and eye Acute percutaneous LD50 for rats >2000 mg/kg. Classified as non-irritating to skin and eyes (rabbits); may cause sensitisation by skin contact. Inhalation LC50 for rats >4646 mg/m3. NOEL NOAEL (2 y) for rats 9.8 mg/kg b.w. daily. ADI 0.1 mg/kg (company proposed) Other Non-mutagenic, non-teratogenic, non-carcinogenic; no adverse effects on reproduction. Toxicity class WHO (a.i.) III (company classification)

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